Grant-in-Aid for Scientific Research on Innovative Areas FY2017-2021Hybrid Catalysis

Yasuhiro Yamashita » Japanese

Affiliation School of Science, The University of Tokyo
Position Associate Professor
HP http://www.chem.s.u-tokyo.ac.jp/users/synorg/en/index.html
Speciality Synthetic Organic Chemistry
Keyword 有機合成化学

Abstract

In this project, development of hybrid catalyst systems of strong base catalysts and metal catalysts or organocatalysts is focused to achieve efficient activation of stable and easily available organic molecules for stereoselective reactions.

Achievement

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Original papers

  • "Alkyl Potassium-Catalyzed Benzylic C–H Alkylation of Alkylarenes with Alkenes"
    Sato, I.; *Yamashita, Y.; *Kobayashi S.
    Synthesis, 1/2019, 51(01), 240-250
  • "Catalytic alkylation reactions of weakly acidic carbonyl and related compounds using alkenes as electrophiles"
    Yamashita, Y.; Igarashi, R.; Suzuki, H.; *Kobayashi, S.
    Org. Biomol. Chem., 8/22/2018, 16(33), 5969-5972
  • "Catalytic Direct‐type Addition Reactions of Alkylarenes with Imines and Alkenes"
    Yamashita, Y.; Suzuki, H.; Sato, I.; Hirata, T.; *Kobayashi, S.
    Angew. Chem. Int. Ed. , 6/4/2018, 57(23), 6896-6900
  • "Catalytic Addition Reactions of Alkylazaarenes to Vinylsilanes"
    Yamashita, Y.; Minami, K.; *Kobayashi, S.
    Chem. Lett., 5/2018, 47(5), 680-692
  • "Catalytic Carbon–Carbon Bond-Forming Reactions of Weakly Acidic Carbon Pronucleophiles Using Strong Brønsted Bases as Catalysts"
    Yamashita, Y.; *Kobayashi, S.
    Chemistry – A European Journal, 1/2/2018, 24(1), 10-17

Review

  • 「Catalytic enantioselective aldol reactions」 Yamashita, Y.; Yasukawa, T.; Yoo, W.-J.; Kitanosono, T.; *Kobayashi, S., Chemical Society Reviews, 47, 4388-4480, 12, 6/18/2018

Conference

  • The Ninth International Forum on Chemistry of Functional Organic Chemicals (IFOC-9)
    "Catalytic Addition Reactions of Alkylarenes with Imines and Alkenes", ポスター発表
    Hirata, T.; Yamashita, Y.; Suzuki, H.; Sato, I.; Kobayashi, S.
    11/18/2018-11/19/2018, 東京大学(東京), 日本