| Affiliation | Tokyo Institute of Technology, School of Science |  |
|---|---|---|
| Position | Associate Professor | |
| Speciality | Synthetic Organic Chemistry, Organometallic Chemistry, Coordination Chemistry | |
| Keyword | Transition Metal Catalyst, Ligand Design, Molecular Transformation of Unreactive Molecule | |
| Institute | The Chemical Society of Japan, The Society of Synthetic Organic Chemistry, Japan, The Society of Silicon Chemistry Japan, American Chemical Society | |
Abstract
Title: Development of New Transformation of sp3C-H Bonds Utilizing Rationally Designed Hybrid Bimetallic Catalysts
Abstract: New transformation of unreactive C-H bonds will be achieved by utilizing newly developed HYBRID bimetallic complexes having a metal-metal bond. The unique cooperative catalysis of two metals will enable efficient coupling reactions and functionalization reactions of various C-H bonds, demonstrating high practical utility of the HYBRID catalysis in synthetic organic chemistry.
Achievement
Original papers
- "Ru-Catalyzed ortho C–H Borylation of Arylphosphines"
Fukuda, K.; Iwasawa, N.; *Takaya, J.
Angew. Chem., Int. Ed., 1/20/2019, 58, 2850-2853 - "Synthesis, Structure, and Reactivity of a Mononuclear η2‐(Ge–H)palladium(0) Complex Bearing a PGeP‐Pincer‐Type Germyl Ligand: Reactivity Differences between Silicon and Germanium"
Takaya, J.; *Iwasawa, N.
European Journal of Inorganic Chemistry, 10/20/2018, 2018, 5012–5018
Conference
- The 14th International Kyoto Conference on New Aspects of Organic Chemistry
"Ru-Catalyzed C–H Borylation of Arylphosphines: A Powerful Tool for Modification of Phosphine Ligands", 口頭発表
Kazuishi Fukuda, Ryosuke Yamada, Nobuharu Iwasawa, Jun Takaya
11/12/2018-11/16/2018, Kyoto, Japan - FHI-JST Joint Symposium
"Exploring New Transition Metal Catalysis Utilizing Rationally Designed Metalloligands", ポスター発表
Takaya, J.
10/31/2018-11/2/2018, Berlin, Germany - International Conference on Coordination Chemistry, 2018
"Exploring New Transition Metal Catalysis Utilizing Rationally Designed Group 13 Metalloligands", 基調講演
Takaya, J.
7/30/2018-8/4/2018, Sendai, Japan - 4th International Conference on Organometallic and Catalysis 2018
"Exploring New Transition Metal Catalysis Utilizing Rationally Designed Group 13 Metalloligands", 招待講演
Takaya, J.
6/22/2018-6/25/2018, Taipei, Taiwan - The 1st Sino-Japanese Symposium on Catalysis for Precision Synthesis
"Exploring New Transition Metal Catalysis Utilizing Rationally Designed Metalloligands", 招待講演
Takaya, J.
5/27/2018-5/30/2018, Shanghai, China
Domestic Conference
- 第8回 CSJ化学フェスタ2018 コラボレーション企画 「1+1は3？」ハイブリッド触媒が紡ぎ出す新反応化学
"金属ハイブリッド触媒 〜どう作るか？ 何ができるか？〜", 招待講演
Takaya, J.
10/23/2018-10/23/2018, 東京 - 第65回有機金属化学討論会
"Highly Efficient Hydrosilylation Reactions Catalyzed by Al–Pd Bimetallic Complexes", 口頭発表
Jun Takaya, Akira Shiozuka, Narumasa Saito, Nobuharu Iwasawa
9/19/2018-9/21/2018, 京都