Grant-in-Aid for Scientific Research on Innovative Areas FY2017-2021Hybrid Catalysis

Jun Takaya » Japanese

Affiliation Tokyo Institute of Technology, School of Science
Position Associate Professor
Speciality Synthetic Organic Chemistry, Organometallic Chemistry, Coordination Chemistry
Keyword Transition Metal Catalyst, Ligand Design, Molecular Transformation of Unreactive Molecule
Institute The Chemical Society of Japan, The Society of Synthetic Organic Chemistry, Japan, The Society of Silicon Chemistry Japan, American Chemical Society

Abstract

Title: Development of New Transformation of sp3C-H Bonds Utilizing Rationally Designed Hybrid Bimetallic Catalysts
Abstract: New transformation of unreactive C-H bonds will be achieved by utilizing newly developed HYBRID bimetallic complexes having a metal-metal bond. The unique cooperative catalysis of two metals will enable efficient coupling reactions and functionalization reactions of various C-H bonds, demonstrating high practical utility of the HYBRID catalysis in synthetic organic chemistry.

Achievement

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Original papers

  • "Ru-Catalyzed ortho C–H Borylation of Arylphosphines"
    Fukuda, K.; Iwasawa, N.; *Takaya, J.
    Angew. Chem., Int. Ed., 1/20/2019, 58, 2850-2853
  • "Synthesis, Structure, and Reactivity of a Mononuclear η2‐(Ge–H)palladium(0) Complex Bearing a PGeP‐Pincer‐Type Germyl Ligand: Reactivity Differences between Silicon and Germanium"
    Takaya, J.; *Iwasawa, N.
    European Journal of Inorganic Chemistry, 10/20/2018, 2018, 5012–5018

Conference

  • The 14th International Kyoto Conference on New Aspects of Organic Chemistry
    "Ru-Catalyzed C–H Borylation of Arylphosphines: A Powerful Tool for Modification of Phosphine Ligands", 口頭発表
    Kazuishi Fukuda, Ryosuke Yamada, Nobuharu Iwasawa, Jun Takaya
    11/12/2018-11/16/2018, Kyoto, Japan
  • FHI-JST Joint Symposium
    "Exploring New Transition Metal Catalysis Utilizing Rationally Designed Metalloligands", ポスター発表
    Takaya, J.
    10/31/2018-11/2/2018, Berlin, Germany
  • International Conference on Coordination Chemistry, 2018
    "Exploring New Transition Metal Catalysis Utilizing Rationally Designed Group 13 Metalloligands", 基調講演
    Takaya, J.
    7/30/2018-8/4/2018, Sendai, Japan
  • 4th International Conference on Organometallic and Catalysis 2018
    "Exploring New Transition Metal Catalysis Utilizing Rationally Designed Group 13 Metalloligands", 招待講演
    Takaya, J.
    6/22/2018-6/25/2018, Taipei, Taiwan
  • The 1st Sino-Japanese Symposium on Catalysis for Precision Synthesis
    "Exploring New Transition Metal Catalysis Utilizing Rationally Designed Metalloligands", 招待講演
    Takaya, J.
    5/27/2018-5/30/2018, Shanghai, China

Domestic Conference

  • 第8回 CSJ化学フェスタ2018 コラボレーション企画 「1+1は3?」ハイブリッド触媒が紡ぎ出す新反応化学
    "金属ハイブリッド触媒 〜どう作るか? 何ができるか?〜", 招待講演
    Takaya, J.
    10/23/2018-10/23/2018, 東京
  • 第65回有機金属化学討論会
    "Highly Efficient Hydrosilylation Reactions Catalyzed by Al–Pd Bimetallic Complexes", 口頭発表
    Jun Takaya, Akira Shiozuka, Narumasa Saito, Nobuharu Iwasawa
    9/19/2018-9/21/2018, 京都