Grant-in-Aid for Scientific Research on Innovative Areas FY2017-2021Hybrid Catalysis

Naoki Ishida » Japanese

Affiliation Graduate School of Engineering, Kyoto University
Position Lecturer
Contact Email
HP http://www.sbchem.kyoto-u.ac.jp/murakami-lab/
Speciality Organic Synthesis
Keyword Transition Metal Catalysis
Institute The Chemical Society of Japan/ The Society of Synthetic Organic Chemistry, Japan/Kinka Chemical Society, Japan

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Abstract

This project aims at the development of direct synthetic transformation of hydrocarbons based on a hybrid catalyst system consisting of photo-induced catalysis and transition metal catalysis. Photo-induced catalysis converts hydrocarbons into energetic intermediates, and the ensuing transition metal catalysis combines the energetic intermediates with reagents to furnish coupling products.

Achievement

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Original papers

  • "Dehydrogenative Coupling of Benzylic and Aldehydic C–H Bonds"
    Kawasaki, T.; *Ishida, N.; *Murakami, M.
    Journal of the American Chemical Society, 2/3/2020, 142(7), 3366
  • "Carboxylation of Benzylic and Aliphatic C–H Bonds with CO2 Induced by Light/Ketone/Nickel"
    *Ishida, N.; Masuda, Y.; Imamura, Y.; Yamazaki, K.; *Murakami, M.
    Journal of the American Chemical Society, 11/28/2019, 141(50), 19611
  • "Synthesis of Tofisopam by Way of Photoinduced CO2 Fixation"
    Masuda, Y.; Makita, K.; Ishida, N.; *Murakami, M.
    Chemistry An Asian Journal, 11/5/2019, 14(23), 4189
  • "Photo-assisted Fixation of CO2 onto Aryl Bromides Producing Aromatic Esters"
    *Ishida, N.; Masuda, Y.; Liao, W.; *Murakami, M.
    Chemistry Letters, 8/21/2019, 48(11), 1316
  • "A Strained Vicinal Diol as a Reductant for Coupling of Organyl Halides"
    *Ishida, N.; Masuda, Y.; Sun, F.; Kamae, Y.; *Murakami, M.
    Chemistry Letters, 6/6/2019, 48(9), 1042
  • "Preparation of Ni(cod)2 Using Light as the Source of Energy"
    *Ishida, N.; Kamae, Y.; *Murakami, M.
    Organometallics, 3/18/2019, 38(7), 1413
  • "Light/Palladium-Promoted Benzylic C–H Acylation Using a Benzoyl Group as the Photo-Directing Group"
    Masuda, Y.; Ishida, N.; *Murakami, M.
    Chemistry, An Asian Journal, 12/27/2018, 14(3), 403
  • "Synthesis of 2-Aryloxy-1,3-Dienes from Phenols and Propargyl Carbonates"
    Ishida, N.; Hori, Y.; Okumura, S.; *Murakami, M.
    Journal of the American Chemical Society, 12/19/2018, 141(1), 84
  • "2-Arylsilacyclobutane as a Latent Carbanion Reacting with CO2"
    Ishida, N.; Okumura, S.; Kawasaki, T.; *Murakami, M.
    Angewandte Chemie, International Edition, 7/18/2018, 57(35), 11399

Conference

  • The Fourth International Symposium on C-H Activation
    "Photo-Induced Carboxylation of Methylbenzenes with CO2 via Cooperative Catalysis of Ketone and Nickel", ポスター発表
    Ishida, N.; Masuda, Y.; Imamura, Y.; Yamazaki, K.; Murakami, M.
    8/30/2018-9/2/2018, Yokohama, Japan
  • The Second Japanese-Spanish Symposium on Organic Synthesis
    "Explorations of Metathesis Type Reactions between C–C, C–Si and Si–Si sigma-Bonds", 招待講演
    Ishida, N.
    5/28/2018-5/29/2018, Kyoto, Japan

Domestic Conference

  • The 99th Annual Meeting Special Program “Systemic Catalytic Science"
    "Photo/Metal Hybrid Catalysis for C–H Carboxylation with CO2", 招待講演
    Ishida, N.
    3/16/2019-3/19/2019, Kobe

Award

  • 「Thieme Chemistry Journals Award」
    受賞者：Naoki Ishida
    贈呈元：Thieme
    受賞日：1/7/2019
  • 「Chemist Award BCA 2018」
    受賞者：石田直樹
    贈呈元：公益財団法人 MSD 生命科学財団
    受賞日：12/1/2018

Collaborative Research

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