| Affiliation | Department of Applied Chemistry, Graduate School of Engineering, Osaka University |  |
|---|---|---|
| Position | Professor | |
| Contact | ||
| HP | http://www.chem.eng.osaka-u.ac.jp/~tobisu-lab/English.html | |
| Speciality | Synthetic Organic Chemistry, Transition Metal Catalysis | |
| Keyword | Transition Metal Catalyst、Strong Bond Cleavage | |
| Institute | Chemical Society Japan, Society of Synthetic Organic Chemistry | |
Abstract
New ipso substitution of anisoles is investigate by the combination of nickel-catalyzed C-O activation and electrolytic reactions. In addition, C-H/C-H cross-coupling of alkanes and arenes is pursued by combining dehydrogenation/isomerization/terminal-selective hydroarylation.
Achievement
Original papers
- "Aryne-Induced SNAr/Dearylation Strategy for the Synthesis ofFluorinated Dibenzophospholes from Triarylphosphines via a P(V)Intermediate"
Fujimoto, H.; Kusano, M.; Kodama, T.; Tobisu, M.
Org. Lett., 3/2/2020, 22, 2293−2297 - "N-Heterocyclic Carbene Catalyzed ConcertedNucleophilic AromaticSubstitution of Aryl Fluorides Bearing a,b-Unsaturated Amides"
Yasui, K.; Kamitani, M.; Tobisu, M.
Angew. Chem. Int. Ed., 8/27/2019, 58, 14157-14161 - "Cyclization of Bisphosphines to Phosphacycles via the Cleavage ofTwo Carbon−Phosphorus Bonds by Nickel Catalysis"
Fujimoto, H.; Kusano, M.; Kodama, T.; Tobisu, M.
Org. Lett., 5/22/2019, 21, 4177−4181
Review
- 「Catalytic Synthesis of Heterocycles via the Claevage of Carbon-Heteroatom Bonds」 Kodama, K.; Chatani, N.; Tobisu, M.*, J. Synth. Org. Chem. Jpn., 76, 1185-1196, 11/1/2018
Conference
- International Kyoto Conference on New Aspects of Organic Synthesis
"Nickel-Mediated Decarbonylation and Decarboxylation of Simple Carbonyl Compounds", 口頭発表
Tobisu, M.
Kyoto, Japan - The 10th Singapore International Chemistry Conference
"Nickel-Mediated Decarbonylation of Simple Ketones", 招待講演
Tobisu, M.
Singapore, Singapore - 4th International Conference on Organometallic and Catalysis
"Nickel-Mediated Decarbonylation of Simple Ketones", 招待講演
Tobisu, M.
Taipei, Taiwan
Domestic Conference
- 第35回 有機合成セミナ－
"不活性結合の触媒的変換反応", 招待講演
Tobisu, M.
天童市、山形県
Award
- 「Mukaiyama Award」
受賞者：Tobisu, M.
贈呈元：有機合成化学協会
受賞日：9/20/2018