Grant-in-Aid for Scientific Research on Innovative Areas FY2017-2021Hybrid Catalysis

Mamoru Tobisu » Japanese

Affiliation Department of Applied Chemistry, Graduate School of Engineering, Osaka University
Position Professor
Contact Email
Speciality Synthetic Organic Chemistry, Transition Metal Catalysis
Keyword Transition Metal Catalyst、Strong Bond Cleavage
Institute Chemical Society Japan, Society of Synthetic Organic Chemistry


New ipso substitution of anisoles is investigate by the combination of nickel-catalyzed C-O activation and electrolytic reactions. In addition, C-H/C-H cross-coupling of alkanes and arenes is pursued by combining dehydrogenation/isomerization/terminal-selective hydroarylation.


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Original papers

  • "Aryne-Induced SNAr/Dearylation Strategy for the Synthesis ofFluorinated Dibenzophospholes from Triarylphosphines via a P(V)Intermediate"
    Fujimoto, H.; Kusano, M.; Kodama, T.; Tobisu, M.
    Org. Lett., 3/2/2020, 22, 2293−2297
  • "N-Heterocyclic Carbene Catalyzed ConcertedNucleophilic AromaticSubstitution of Aryl Fluorides Bearing a,b-Unsaturated Amides"
    Yasui, K.; Kamitani, M.; Tobisu, M.
    Angew. Chem. Int. Ed., 8/27/2019, 58, 14157-14161
  • "Cyclization of Bisphosphines to Phosphacycles via the Cleavage ofTwo Carbon−Phosphorus Bonds by Nickel Catalysis"
    Fujimoto, H.; Kusano, M.; Kodama, T.; Tobisu, M.
    Org. Lett., 5/22/2019, 21, 4177−4181


  • 「Catalytic Synthesis of Heterocycles via the Claevage of Carbon-Heteroatom Bonds」 Kodama, K.; Chatani, N.; Tobisu, M.*, J. Synth. Org. Chem. Jpn., 76, 1185-1196, 11/1/2018


  • International Kyoto Conference on New Aspects of Organic Synthesis
    "Nickel-Mediated Decarbonylation and Decarboxylation of Simple Carbonyl Compounds", 口頭発表
    Tobisu, M.
    Kyoto, Japan
  • The 10th Singapore International Chemistry Conference
    "Nickel-Mediated Decarbonylation of Simple Ketones", 招待講演
    Tobisu, M.
    Singapore, Singapore
  • 4th International Conference on Organometallic and Catalysis
    "Nickel-Mediated Decarbonylation of Simple Ketones", 招待講演
    Tobisu, M.
    Taipei, Taiwan

Domestic Conference

  • 第35回 有機合成セミナ-
    "不活性結合の触媒的変換反応", 招待講演
    Tobisu, M.


  • 「Mukaiyama Award」
    受賞者:Tobisu, M.