Grant-in-Aid for Scientific Research on Innovative Areas FY2017-2021Hybrid Catalysis

Masahiro Yamanaka » Japanese

Affiliation Rikkyo University, Faculty of Science
Position professor
Contact Email
Speciality Organic chemistry, Computational chemistry
Keyword Asymmetric Catalyst, Catalyst Design, DFT Calculation
Institute The Chemical Society of Japan, The society of Synthetic Organic Chemistry Japan, The Japanese Photochemistry Association


『Clarification and Design of Hybrid Control System Consisting of Multiple Cooperative Interactions』

Based on collaborations with experimental studies, we elucidate the cooperative effect of "Lewis acid/base interaction", "hydrogen bond interaction", and "dispersion interaction", rationally designing HYBRID molecular catalysts.


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Original papers

  • "Catalysis based on C-I・・・π halogen bonds: electrophilic activation of 2-alkenylindoles by cationic halogen-bond donors for [4+2] cycloadditions"
    Kuwano, S.; Suzuki, T.; Yamanaka, M.; Tsutsumi, R.; *Arai, T.
    Angew. Chem.Int. Ed.,2019, 58(30), 10220-10224
  • "BINOL-derived bifunctional sulfide catalysts for asymmetric synthesis of 3,3-disubstituted phthalides via bromolactonization"
    Okada, M.; Kaneko, K.; Yamanaka, M.; Shirakawa, S.
    Org. Biomol. Chem.,2019, 17(15), 3747-3751
  • "Mechanism and Origin of Stereoselectivity in Chiral Phosphoric Acid‐Catalysed Aldol‐Type Reactions of Azlactones with Vinyl Ethers"
    Kanomata, K.; Nagasawa, Y.; Shibata, Y.; *Yamanaka, M.; Egawa, F.; Kikuchi, J.; *Terada, M.
    Chem. Eur. J., 2/2020, 26, 3364-3372
  • "Insights into the Structure and Function of a Chiral Conjugate-Base-Stabilized Bronsted Acid Catalyst"
    Odagi, M.; Araki, H.; Min, C.; Yamamoto, E.; Emge, T. J.; *Yamanaka, M.; *Seidel, D.
    Eur. J. Org. Chem. ,2019, 486-492
  • "Design of Chiral Bifunctional Dialkyl Sulfide Catalysts for Regio-, Diastereo-, and Enantioselective Bromolactonization"
    Nishiyori, R.; Tsuchihashi, A.; Mochizuki, A.; Kaneko, K.; *Yamanaka, M.; *Shirakawa, S.
    Chem. Eur. J. ,2018, 24, 16747-16752


  • 2nd ICReDD International Symposium
    "The Interplay between Experiment and Computation: Rational Design of Chiral Space in Asymmetric Catalysis", 招待講演
    Yamanaka, M.
    11/27/2019-11/29/2019, Sapporo, Japan

Domestic Conference

  • 第100春季年会
    "水素結合を利用したイリジウム触媒によるチオアニソール類のオルト位選択的なC-Hボリル化", 口頭発表
    3/22/2020-3/25/2020, 東京理科大学野田キャンパス
  • 第100春季年会
    "キラル二官能性スルフィド触媒によるブロモラクトン化反応を利用した 3,3-二置換フタリドの不斉合成", ポスター発表
    3/22/2020-3/25/2020, 東京理科大学野田キャンパス
  • 第100春季年会
    "銅(II)ビスアミジン触媒によるインドールとβ,γ-不飽和αケトエステルの不斉 Friedel-Crafts 反応", 口頭発表
    3/22/2020-3/25/2020, 東京理科大学野田キャンパス
  • 第100春季年会
    "新規ビピリジン-ウレア配位子を用いたα,β-不飽和カルボニル化合物に対する不斉ホウ素化反応の開発", 口頭発表
    3/22/2020-3/25/2020, 東京理科大学野田キャンパス