Grant-in-Aid for Scientific Research on Innovative Areas FY2017-2021Hybrid Catalysis

Masami Kamigaito » Japanese

Affiliation Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University
Position Professor
Contact Email
HP http://chembio.nagoya-u.ac.jp/labhp/polymer2/en/index_e.html
Speciality Polymer Chemistry
Keyword Precision Polymerization, Precision Polymer Synthesis, Living Polymerization, Monomer Sequence Control, Bio-based Polymer
Institute The Society of Polymer Science Japan, The Chemcal Society of Japan, The Society of Synthetic Organic Chemistry Japan, American Chemical Society, The Royal Society of Chemistry

Abstract

◆Research Topics:
Multifactor Control of Vinyl Polymer Structures by Hybrid Precision Polymerization

◆Research Summary:
The synthesis of multifactor controlled polymers in terms of molecular weight, stereoregularity, monomer sequence, etc. is one of the ultimate goals in polymer chemistry. To attain this goal, it is necessary to develop hybrid catalytic systems that can work concertedly or independently to enable the simultaneous controls not only via catalytic sites but also via weak interactions. This study is directed to developments of hybrid precision polymerization for multifactor control of molecular weights, stereostructures, and monomer sequences of vinyl polymers by radical and cationic polymerizations, which will lead to novel functional polymeric materials.

Achievement

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Original papers

  • "Terpenoid-Derived Conjugated Dienes with exo-Methylene and a 6-Membered Ring: High Cationic Reactivity, Regioselective Living Cationic Polymerization, and Random and Block Copolymerization with Vinyl Ethers"
    Nishida, T.; Satoh, K.; *Tamura, M.; Li, Y.; Tomishige, K.; Caillol, S.; Ladmiral, V.; Vayer, M.; Mahut, F.; *Sinturel, C.; *Kamigaito, M.
    Polym. Chem., 3/7/2021, 12(9), 1186-1198
  • "Sequence-Regulated Vinyl Polymers via Iterative Atom Transfer Radical Additions and Acyclic Diene Metathesis Polymerization"
    Miyajima, M.; Satoh, K.; *Kamigaito, M.
    Polym. Chem., 1/21/2021, 12(3), 423-431
  • "Biobased Polymers via Radical Homopolymerization and Copolymerization of a Series of Terpenoid-Derived Conjugated Dienes with exo-Methylene and 6-Membered Ring"
    Nishida, T.; Satoh, K.; *Kamigaito, M.
    Molecules, 12/12/2020, 25(24), 5890
  • "Multifactor Control of Vinyl Monomer Sequence, Molecular Weight, and Tacticity via Iterative Radical Additions and Olefin Metathesis Reactions"
    Miyajima, M.; Satoh, K.; Horibe, T.; Ishihara, K.; *Kamigaito, M.
    J. Am. Chem. Soc., 11/4/2020, 142(44), 18955-18962
  • "Bio-Based Cycloolefin Polymers: Carvone-Derived Cyclic Conjugated Diene with Reactive exo-Methylene Group for Regioselective and Stereospecific Living Cationic Polymerization"
    Nishida, T.; Satoh, K.; Nagano, S.; Seki, T.; Tamura, M.; Li, Y.; Tomishige, K.; *Kamigaito, M.
    ACS Macro Lett., 8/8/2020, 9(8), 1178-1183
  • "1:3 ABAA Sequence-Regulated Substituted Polymethylenes via Alternating Radical Copolymerization of Methyl Cinnamate and Maleic Anhydride Followed by Post-Polymerization Reactions"
    Terao, Y.; Sugihara, S.; *Satoh, K.; *Kamigaito, M.
    Eur. Polym. J., 11/2019, 120, 109225
  • "Cationic Polymerization via Activation of Alkoxyamines Using Photoredox Catalysts"
    Konya, M.; Uchiyama, M.; Satoh, K.; *Kamigaito, M.
    ChemPhotoChem, 11/2019, 3(11), 1100-1108
  • "Cooperative Reduction of Various RAFT Polymer Terminals using Hydrosilane and Thiol via Polarity Reversal Catalysis"
    Uchiyama, M.; *Satoh, K.; *Kamigaito, M.
    Chem. Commun., 5/10/2019, 55(37), 5327-5330
  • "Valencene as a Naturally Occurring Sesquiterpene Monomer for Radical Copolymerization with Maleimide to Induce Concurrent 1:1 and 1:2 Propagation"
    Hashimoto, H.; Takeshima, K.; Nagai, T.; Uchiyama, M.; *Satoh, K.; *Kamigaito, M.
    Polym. Degrad. Stab., 3/2019, 161, 183-190
  • "Controlled Radical Copolymerization of Cinnamic Derivatives as Renewable Vinyl Monomers with Both Acrylic and Styrenic Substituents: Reactivity, Regioselectivity, Properties, and Functions"
    Terao, Y.; *Satoh, K.; *Kamigaito, M.
    Biomacromolecules, 1/14/2019, 20(1), 192-203

Review

  • 「Progress and Perspectives beyond Traditional RAFT Polymerization」 Nothling, M. D.; Fu, Q.; Reyhani, A.; Allison-Logan, S.; Jung, K.; Zhu, J.; *Kamigaito, M.; *Boyer, C.; *Qiao, G. G. , Adv. Sci., 7, 2001656, 20, 10/21/2020
  • 「Synergistic Advances in Living Cationic and Radical Polymerizations」 *Kamigaito, M.; *Sawamoto, M., Macromolecules, 53, 6749-6753, 16, 8/25/2020
  • 「Degenerative Chain-Transfer Process: Controlling All Chain-Growth Polymerizations and Enabling Novel Monomer Sequences」 *Kamigaito, M.; Satoh, K.; Uchiyama, M., J. Polym. Sci., Part A, Polym. Chem., 57, 243-254, 3, 2/1/2019

Conference

  • The 16th Pacific Polymer Conference (PPC16)
    "Vinyl Monomer Sequence Control via Precision Polymerization", 招待講演
    Kamigaito, M.
    12/8/2019-12/12/2019, Singapore, Singapore
  • 13th IUPAC International Symposium on Ionic Polymerization (IP19)
    "Cationic Degenerative Chain-Transfer Polymerization for Precision Polymer Synthesis", 招待講演
    Uchiyama, M.; Satoh, K., Kamigaito, M.
    9/8/2019-9/13/2019, Beijing, China
  • Precision Synthesis and Thin Film Self-Assembly of Polymers
    "Vinyl Monomer Sequence Control via Precision Polymerization", 招待講演
    Kamigaito, M.
    7/25/2019-7/25/2019, Montpellier, France
  • 2019 Japan-USA Symposium on Polymer Chemistry: Macromolecules: - Challenges and Opportunities for the 21st Century -
    "Vinyl Monomer Sequence Control via Precision Polymerization", 招待講演
    Kamigaito, M.
    6/18/2019-6/21/2019, Stanford, USA
  • 2nd International Conference of Molecular Engineering of Polymers (MEP-2018, MEP-2)
    "Monomer Sequence Regulation via Controlled Additions and Polymerizations", 基調講演
    Kamigaito, M.; Satoh, K.
    9/20/2018-9/23/2018, Shanghai, China
  • Japan-Korea Joint Symposium on Polymer Science 2018
    "Monomer Sequence Regulation via Controlled Additions and Polymerizations", 招待講演
    Kamigaito, M.
    7/23/2018-7/27/2018, Sapporo, Japan
  • The IUPAC World Polymer Congress (MACRO2018)
    "Vinyl Monomer Sequence Regulation via Controlled Addition and Polymerization", 招待講演
    Kamigaito, M.; Satoh, K.
    7/1/2018-7/5/2018, Cairns, Australia
  • CAMD pre-MACRO Polymer Symposium
    "Precision Polymerization of Renewable Vinyl Monomers", 招待講演
    Kamigaito, M.
    6/29/2018-6/29/2018, Sydney, Australia
  • 17th International Conference “Polymers and Organic Chemistry” (POC2018)
    "Controlled Polymerization of Bio-based Vinyl Monomers", 招待講演
    Kamigaito, M.; Satoh, K.
    6/3/2018-6/7/2018, Palavas Les Flots, France
  • Bordeaux Polymer Conference 2018 (BPC2018)
    "Sequence-Regulated Polymers via Iterative Single Monomer Addition and Controlled Polymerization", 招待講演
    Kamigaito, M.; Satoh, K.; Soejima, T.; Miyajima, M.; Tanaka, Y.
    5/28/2018-5/31/2018, Bordeaux, France

Award

  • 「高分子学会賞」
    受賞者:上垣外正己
    贈呈元:高分子学会
    受賞日:5/28/2020

Media

  • Polym. Chem.
    「Terpenoid-Derived Conjugated Dienes with exo-Methylene and a 6-Membered Ring: High Cationic Reactivity, Regioselective Living Cationic Polymerization, and Random and Block Copolymerization with Vinyl Ethers」
    Nishida, T.; Satoh, K.; Tamura, M.; Li, Y.; Tomishige, K.; Caillol, S.; Ladmiral, V.; Vayer, M.; Mahut, F.; Sinturel, C.; Kamigaito, M., 3/7/2021
    Front Cover
    PDF File
  • 中日新聞
    「環境優しい新材料 期待 名大 高分子の精密合成法を開発」
    Miyajima, M.; Satoh, K.; Horibe, T.; Ishihara, K.; Kamigaito, M., 11/11/2020
  • J. Am. Chem. Soc.
    「Multifactor Control of Vinyl Monomer Sequence, Molecular Weight, and Tacticity via Iterative Radical Additions and Olefin Metathesis Reactions」
    Miyajima, M.; Satoh, K.; Horibe, T.; Ishihara, K.; Kamigaito, M., 11/4/2020
    Supplementary Cover
    PDF File
  • J. Am. Chem. Soc.
    「A New Method Creates Precision Polymers」
    Miyajima, M.; Satoh, K.; Horibe, T.; Ishihara, K.; Kamigaito, M., 10/28/2020
    Spotlights on Recent JACS Publications
    PDF File
  • 化学工業日報
    「ビニルポリマー新合成法 モノマー配列精密制御」
    Miyajima, M.; Satoh, K.; Horibe, T.; Ishihara, K.; Kamigaito, M., 10/22/2020
  • ACS Macro Lett.
    「Bio-Based Cycloolefin Polymers: Carvone-Derived Cyclic Conjugated Diene with Reactive exo-Methylene Group for Regioselective and Stereospecific Living Cationic Polymerization」
    Nishida, T.; Satoh, K.; Nagano, S.; Seki, T.; Tamura, M.; Li, Y.; Tomishige, K.; Kamigaito, M. , 8/8/2020
    Front Cover
    PDF File
  • ChemPhotoChem 2019, 3, 1058
    「Cationic Polymerization via Activation of Alkoxyamines Using Photoredox Catalysts」
    Konya, M.; Uchiyama, M.; Satoh, K.; Kamigaito, M., 11/2019
    Cover Profile
    PDF File
  • ChemPhotoChem 2019, 3, 1100-1108
    「Cationic Polymerization via Activation of Alkoxyamines Using Photoredox Catalysts」
    Konya, M.; Uchiyama, M.; Satoh, K.; Kamigaito, M., 11/2019
    Front Cover
    PDF File
  • Chem. Commun. 2019, 55, 5327-5330
    「Cooperative Reduction of Various RAFT Polymer Terminals using Hydrosilane and Thiol via Polarity Reversal Catalysis」
    Uchiyama, M.; Satoh, K.; Kamigaito, M., 5/10/2019
    Front Cover
    PDF File
  • Biomacromolecules 2019, 20, 192-203
    「Controlled Radical Copolymerization of Cinnamic Derivatives as Renewable Vinyl Monomers with Both Acrylic and Styrenic Substituents: Reactivity, Regioselectivity, Properties, and Functions」
    Terao, Y.; Satoh, K.; Kamigaito, M., 1/14/2019
    Supplementary Cover
    PDF File