Grant-in-Aid for Scientific Research on Innovative Areas FY2017-2021Hybrid Catalysis

Takashi Ooi » Japanese

Affiliation Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Engineering, Nagoya University
Position Professor
Contact Email
HP http://www.chembio.nagoya-u.ac.jp/labhp/organic3/index_e.html
Speciality Chemistry of Catalysis, Synthetic Organic Chemistry, Organometallic Chemistry
Keyword Molecular Catalyst, Catalytic Asymmetric Synthesis, Ionic Reaction, Radical Reaction
Institute The Chemical Society of Japan (CSJ), The Society of Synthetic Organic Chemistry, Japan (SSOCJ), The American Chemical Society (ACS), Royal Society of Chemistry (RSC)

Abstract

Stereodivergent Synthesis Enabled by Hybrid Catalysis

Achievement

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Original papers

  • "Non‐Enzymatic Hybrid Catalysis for Stereoconversion of L‐Amino Acid Derivatives to D‐Isomers"
    Nagato, Y.; Kiyokawa, M.; Ueki, Y.; Kikuchi, J.; Ohmatsu, K.; Terada, M.; *Ooi, T.
    Asian J. Org. Chem., 4/2020, 9(4), 561-565
  • "A Structurally Robust Chiral Borate Ion: Molecular Design, Synthesis, and Asymmetric Catalysis"
    Uraguchi,D.; Ueoka,F.; Tanaka,N.; Kizu,T.; Takahashi,W.;*Ooi,T.
    Angew. Chem. Int. Ed., 3/27/2020, 2020(xx), xxx-xxx
  • "Exploiting Single-Electron Transfer in Lewis Pairs for Catalytic Bond-Forming Reactions"
    Aramaki,Y.; Imaizumi,N.; Hotta,M.; Kumagai,J.; *Ooi,T.
    Chem. Sci., 3/20/2020, 2020(xx), xxx-xxx
  • "Non-Enzymatic Hybrid Catalysis for Stereoconversion of L-Amino Acid Derivatives to D-Isomers"
    Nagato,Y.; Kiyokawa,M.; Ueki,Y.; Kikuchi,J.; Ohmatsu,K.; Terada,M.; *Ooi,T.
    Asian J. Org. Chem., 2/12/2020, 2020(9), 561-565
  • "Unveiling Latent Photoreactivity of Imines"
    Uraguchi,D.; Tsuchiya,Y.; Ohtani,T.; Enomoto,T,; Masaoka,S.; Yokogawa,D.; *Ooi,T.
    Angew. Chem. Int. Ed., 12/14/2019, 2020(59), 3665-3670
  • "Zwitterionic 1,2,3-Triazolium Amidate as a Catalyst for Photoinduced Hydrogen-Atom Transfer Radical Alkylation"
    Ohmatsu,K.; Suzuki,R.; Furukawa,Y.; Sato,M.; *Ooi,T.
    ACS Catal. , 12/2/2019, 2020(10), 2627-2632
  • "Inserting Nitrogen: An Effective Concept To Create Nonplanar and Stimuli-Responsive Perylene Bisimide Analogues"
    Hayakawa,S.; Kawasaki,A.; Hong,Y.; Uraguchi,D.; Ooi,T.; *Kim,D.; *Akutagawa,T.; *Fukui,N.; *Shinokubo,H.
    J. Am. Chem. Soc., 11/20/2019, 2019(141), 19807-19816
  • "Direct allylic C-H alkylation of enol silyl ethers enabled by photoredox-Brønsted base hybrid catalysis"
    Ohmatsu,K.; Nakashima,T.; Sato,M.; *Ooi,T.
    Nat. Commun., 6/20/2019, 2019(10), 2706
  • "Formal Hydroformylation of α,β-Unsaturated Carboxylic Acids under Photoexcited Ketone Catalysis"
    Zhu,K.; Ohtani,T.; Tripathi,B,C.; Uraguchi,D.; *Ooi,T.
    Chem. Lett., 5/25/2019, 2019(48), 715-717
  • "A femtomolar-range suicide germination stimulant for the parasitic plant Striga hermonthica"
    *Uraguchi, D.; Kuwata, K.; Hijikata, Y.; Yamaguchi, R.; Imaizumi, H.; Sathiyanarayanan A. M.; Rakers, C.; Mori, N.; Akiyama, K.; Irle, S.; McCourt, P.; Kinoshita, T.; *Ooi, T.; *Tsuchiya, Y.
    Science ,2018, 362, 1301-1305
  • "Protonated Bis-1,2,3-triazole as an Anion-Binding Chiral Brønsted Acid for Catalytic Asymmetric Friedel-Crafts Reaction of Indoles with Imines"
    Furukawa,Y.; Suzuki, R.; Nakashima, T.; Gramage-Doria, R.; Ohmatsu, K.; *Ooi,T.
    Bull. Chem. Soc. J.,2018, 91(8), 1252-1257
  • "Photocatalytic borylcyclopropanation of α-boryl styrenes"
    Ohtani, T.; Tsuchiya, Y.; Uraguchi, D.; *Ooi, T.
    Org. Chem. Front, 3/20/2019
  • "Catalyst-Directed Guidance of Sulfur-Substituted Enediolates to Stereoselective Carbon-Carbon Bond Formation with Aldehydes"
    Uraguchi,D.; Yamada, K.; Sato, M.; *Ooi, T.
    J. Am. Chem. Soc.,2018, 140, 5110–5117
  • "Catalyst-Enabled Site-divergent Stereoselective Michael Reactions: Overriding Intrinsic Reactivity of Enynyl Carbonyl Acceptors"
    Uraguchi,D.; Shibazaki, R.; Tanaka, N.; Yamada, K.; Yoshioka, K.; *Ooi, T.
    Angew. Chem. Int. Ed.,2018, 57, 4732-4736
  • "Allenedicarboxylate as a Stereochemically Labile Electrophile for Chiral Organic Base-Catalyzed Stereoselective Michael Addition"
    Uraguchi,D.; Kawai, Y.; Sasaki, H.; Yamada, K.; *Ooi, T.
    Chem. Lett.,2018, 47, 594-597
  • "Molecular Design, Synthesis, and Asymmetric Catalysis of a Hexacoordinated Chiral Phosphate Ion"
    Uraguchi,D.; Sasaki, H.; Kimura, Y.; Ito, T.; *Ooi, T.
    J. Am. Chem. Soc.,2018, 140, 2765-2768
  • "Diastereo- and enantioselective phase-transfer alkylation of 3-substituted oxindoles with racemic secondary alkyl halides"
    Ohmatsu,K.; Furukawa, Y.; Kiyokawa, M.; *Ooi, T.
    Chem. Commun.,2017, 53, 13113-13116

Books

  • 「Organic Molecular Catalysts in Radical Chemistry: Challenges Toward Selective Transformations」
    Uraguchi, D.; Ohmatsu, K.; Ooi, T.
    「Molecular Technology: Synthesis Innovation, Volume 4」,Yamamoto, H., Wiley-VCH,2019, 163-197

Conference

  • Symposium on Supramolecular Chemistry in Celebration of Professor Julius Rebek 75th birthday
    "Molecular Design of Organic Ions for Asymmetric Catalysis", 口頭発表
    大井貴史
    10/18/2019-10/18/2019, 上海, 中国
  • The First International Symposium on Molecular Recognition and Synthesis
    "Molecular Design and Asymmetric Catalysis of Weakly-Coordinating Chiral Anions", 招待講演
    大井貴史
    10/13/2019-10/13/2019, 上海, 中国
  • The 14th International Conference on Cutting-Edge Organic Chemistry in Asia
    "「Zwitterionic 1,2,3-Triazolium Amidate as a Catalyst for Photoinduced Hydrogen-Atom Tansfer Radical Alkylation」", ポスター発表
    Takashi, Ooi
    9/28/2019-9/29/2019, 北海道, 日本
  • 2019 International C-H Functionalization Workshop
    "Formal Hydroformylation of α,β-Unsaturated Carboxylic Acids under Photoexcited Ketone Catalysis", ポスター発表
    Zhu,K.; Ohtani,T.; Tripathi,C.B.; Uraguchi,D.; Ooi,T.
    7/11/2019-7/12/2019, Daejeon, South Korea
  • 2019 International C-H Functionalization Workshop
    "Zwitterionic 1,2,3-Triazolium Amidate as a Catalyst for Photoinduced Hydrogen-Atom Transfer Radical Alkylation", ポスター発表
    Suzuki,R.; Ohmatsu,K.; Ooi,T.
    7/11/2019-7/12/2019, Daejeon, South Korea
  • 2019 International C-H Functionalization Workshop
    "Divergence in Photoredox Reaction: Radical Addition of α-Bromo Nitroalkanes to Styrene Derivatives", 口頭発表
    Tsuchiya,Y.; Onai,R.; Uraguchi,D.; Ooi,T.
    7/11/2019-7/12/2019, Daejeon, South Korea
  • Markovnikov Congress on Organic Chemistry
    "Molecular Design and Asymmetric Catalysis of Weakly-Coordinating Chiral Anions", 招待講演
    Ooi, T.
    6/24/2019-6/27/2019, Kazan, Russia
  • The 1st International Symposium on Hybrid Catalysis for Enabling Molecular Synthesis on Demand
    "Zwitterionic 1,2,3-Triazolium Amidate as a Catalyst for Photoinduced Hydrogen-Atom Transfer Radical Alkylation", ポスター発表
    Suzuki,R.; Ohmatsu,K.; Ooi,T.
    5/30/2019-5/31/2019, Tokyo, Japan
  • The 1st International Symposium on Hybrid Catalysis for Enabling Molecular Synthesis on Demand
    "Divergence in Photoredox Reaction: Radical Addition of α-Bromo Nitroalkanes to Styrene Derivatives", ポスター発表
    Onai,R.; Tsuchiya,Y.; Uraguchi,D.; Ooi,T.
    5/30/2019-5/31/2019, Tokyo, Japan
  • The 1st International Symposium on Hybrid Catalysis for Enabling Molecular Synthesis on Demand
    "Palladium-Halide Ion Hybrid Catalysis for Base-Free Allylation of Carbonyl Compounds with Allylic Carbonates", ポスター発表
    Matsuyama,N.; Ohmatsu,K.; Ooi,T.
    5/30/2019-5/31/2019, Tokyo, Japan
  • SCS Lectureships 2019
    "Behavior of Molecules: From Catalysis to Biological Functions", 招待講演
    Ooi, T.
    5/20/2019-5/24/2019, Geneve, Fribourg, Lausanne, Basel, Zurich, Swiss
  • Advances in Organocatalysis, SCI
    "Molecular design of organic ions for asymmetric catalysis", 招待講演
    Ooi, T.
    2/25/2019, London, UK
  • International Conference on Organometallics and Catalysis
    "Molecular Design and Asymmetric Catalysis of Weakly-Coordinating Chiral Anions", 招待講演
    Ooi, T.
    12/13/2018-12/16/2018, Cavelossim, India
  • ICCC 2018: Post Conference in Nagasaki
    "Molecular Design of Organic Ion Pairs for Asymmetric Catalysis", 招待講演
    Ooi, T.
    11/27/2018-11/30/2018, Nagasaki, Japan
  • Chinese Chemical Society Chemistry Congress
    "Molecular Design of Organic Ion Pairs for Asymmetric Catalysis", 招待講演
    Ooi, T.
    5/6/2018-5/8/2018, Chengdu, China
  • 1st International Symposium on Catalysis for Sustainable Chemical Synthesis
    "Molecular Design of Organic Ion Pairs for Asymmetric Catalysis", 招待講演
    Ooi, T.
    9/25/2017-9/26/2017, Freiburg, Germany
  • 1st International Symposium on Catalysis for Sustainable Chemical Synthesis
    "Catalytic Asymmetric Strecker Reaction of Ketoimines with Potassium Cyanide", ポスター発表
    Morita, Y.; Ohmatsu, K.; Ooi, T.
    9/25/2017-9/26/2017, Freibrug, Germany
  • 1st International Symposium on Catalysis for Sustainable Chemical Synthesis
    "Stereoselective Mannich-type Reaction of Aromatic Lactams under the Catalysis of Chiral Ammonium Betaines", ポスター発表
    Kato, K.; Uraguchi, D.; Ooi, T.
    9/25/2017-9/26/2017, Freibrug, Germany

Award

  • 「Swiss Chemical Society Lectureships 2019」
    受賞者:Takashi Ooi
    贈呈元:Swiss Chemical Society
    受賞日:5/20/2019