| Affiliation | Institute of Transformative Bio-Molecules (WPI-ITbM) and Graduate School of Engineering, Nagoya University |  |
|---|---|---|
| Position | Professor | |
| Contact | ||
| HP | http://www.chembio.nagoya-u.ac.jp/labhp/organic3/index_e.html | |
| Speciality | Chemistry of Catalysis, Synthetic Organic Chemistry, Organometallic Chemistry | |
| Keyword | Molecular Catalyst, Catalytic Asymmetric Synthesis, Ionic Reaction, Radical Reaction | |
| Institute | The Chemical Society of Japan (CSJ), The Society of Synthetic Organic Chemistry, Japan (SSOCJ), The American Chemical Society (ACS), Royal Society of Chemistry (RSC) | |
Abstract
Stereodivergent Synthesis Enabled by Hybrid Catalysis
Achievement
Original papers
- "Hybrid Catalysis of 8-Quinolinecarboxaldehyde and Br?nsted Acid for Efficient Racemization of α-Amino Amides and Its Application in Chemoenzymatic Dynamic Kinetic Resolution"
Ohmatsu,K.; Kiyokawa,M.; Shirai,Y.; Nagato,Y.; Ooi,T.
HETEROCYCLES, 2021(103), xxx-xxx - "Catalytic Asymmetric Synthesis of 5-Membered Alicyclic α-Quaternary β-Amino Acids via [3+2]-Photocycloaddition of α-Substituted Acrylates"
Kimura,Y.; Uraguchi,D.; Ooi,T.
Org. Biomol. Chem., 2/3/2021, 2021(19), 1744-1747 - "o-Quinone Methide with Overcrowded Olefin Component as a Dehydridation Catalyst under Aerobic Photoirradiation Conditions"
Uraguchi,D.; Kato,K.; Ooi,T.
Chem. Sci. , 1/15/2021, 2021(12), 2778-2783 - "Urea as a Redox-Active Directing Group under Asymmetric Photocatalysis of Iridium-Chiral Borate Ion Pairs"
Uraguchi,D.; Kimura,Y.; Ueoka,F.; Ooi,T.
J. Am. Chem. Soc. , 11/5/2020, 2020(142), 19462-19467 - "Mannich-type allylic C-H functionalization of enol silyl ethers under photoredox-thiol hybrid catalysis"
Nakashima,T.; Ohmatsu,K.; Ooi,T.
Org. Biomol. Chem. , 9/23/2020, 2020(56), 11014-11017 - "Redox-Regulated Divergence in Photocatalytic Addition of α-Nitro Alkyl Radicals to Styrenes"
Tsuchiya,Y.; Onai,R.; Uraguchi,D.; Ooi,T.
Chem. Commun., 8/4/2020, 2020(56), 11014-11017 - "Ion-Paired Ligands for Palladium-Catalyzed Allylic Alkylation under Base-Free Conditions"
Ohmatsu,K.; Matsuyama,N.; Nagato,Y.; Ooi,T.
Chem. Lett. , 6/26/2020, 2020( 49), 1114-1116 - "Non‐Enzymatic Hybrid Catalysis for Stereoconversion of L‐Amino Acid Derivatives to D‐Isomers"
Nagato, Y.; Kiyokawa, M.; Ueki, Y.; Kikuchi, J.; Ohmatsu, K.; Terada, M.; *Ooi, T.
Asian J. Org. Chem., 4/8/2020, 9(4), 561-565 - "A Structurally Robust Chiral Borate Ion: Molecular Design, Synthesis, and Asymmetric Catalysis"
Uraguchi,D.; Ueoka,F.; Tanaka,N.; Kizu,T.; Takahashi,W.;＊Ooi,T.
Angew. Chem. Int. Ed., 3/27/2020, 2020(59), 11456-11461 - "Exploiting Single-Electron Transfer in Lewis Pairs for Catalytic Bond-Forming Reactions"
Aramaki,Y.; Imaizumi,N.; Hotta,M.; Kumagai,J.; *Ooi,T.
Chem. Sci., 3/20/2020, 2020(11), 4305-4311 - "Non-Enzymatic Hybrid Catalysis for Stereoconversion of L-Amino Acid Derivatives to D-Isomers"
Nagato,Y.; Kiyokawa,M.; Ueki,Y.; Kikuchi,J.; Ohmatsu,K.; Terada,M.; *Ooi,T.
Asian J. Org. Chem., 2/12/2020, 2020(9), 561-565 - "Unveiling Latent Photoreactivity of Imines"
Uraguchi,D.; Tsuchiya,Y.; Ohtani,T.; Enomoto,T,; Masaoka,S.; Yokogawa,D.; *Ooi,T.
Angew. Chem. Int. Ed., 12/14/2019, 2020(59), 3665-3670 - "Zwitterionic 1,2,3-Triazolium Amidate as a Catalyst for Photoinduced Hydrogen-Atom Transfer Radical Alkylation"
Ohmatsu,K.; Suzuki,R.; Furukawa,Y.; Sato,M.; *Ooi,T.
ACS Catal. , 12/2/2019, 2020(10), 2627-2632 - "Inserting Nitrogen: An Effective Concept To Create Nonplanar and Stimuli-Responsive Perylene Bisimide Analogues"
Hayakawa,S.; Kawasaki,A.; Hong,Y.; Uraguchi,D.; Ooi,T.; *Kim,D.; *Akutagawa,T.; *Fukui,N.; *Shinokubo,H.
J. Am. Chem. Soc., 11/20/2019, 2019(141), 19807-19816 - "Direct allylic C-H alkylation of enol silyl ethers enabled by photoredox-Brønsted base hybrid catalysis"
Ohmatsu,K.; Nakashima,T.; Sato,M.; *Ooi,T.
Nat. Commun., 6/20/2019, 2019(10), 2706 - "Formal Hydroformylation of α,β-Unsaturated Carboxylic Acids under Photoexcited Ketone Catalysis"
Zhu,K.; Ohtani,T.; Tripathi,B,C.; Uraguchi,D.; *Ooi,T.
Chem. Lett., 5/25/2019, 2019(48), 715-717 - "A femtomolar-range suicide germination stimulant for the parasitic plant Striga hermonthica"
*Uraguchi, D.; Kuwata, K.; Hijikata, Y.; Yamaguchi, R.; Imaizumi, H.; Sathiyanarayanan A. M.; Rakers, C.; Mori, N.; Akiyama, K.; Irle, S.; McCourt, P.; Kinoshita, T.; *Ooi, T.; *Tsuchiya, Y.
Science ,2018, 362, 1301-1305 - "Protonated Bis-1,2,3-triazole as an Anion-Binding Chiral Brønsted Acid for Catalytic Asymmetric Friedel-Crafts Reaction of Indoles with Imines"
Furukawa,Y.; Suzuki, R.; Nakashima, T.; Gramage-Doria, R.; Ohmatsu, K.; *Ooi,T.
Bull. Chem. Soc. J.,2018, 91(8), 1252-1257 - "Photocatalytic borylcyclopropanation of α-boryl styrenes"
Ohtani, T.; Tsuchiya, Y.; Uraguchi, D.; *Ooi, T.
Org. Chem. Front, 3/20/2019 - "Catalyst-Directed Guidance of Sulfur-Substituted Enediolates to Stereoselective Carbon-Carbon Bond Formation with Aldehydes"
Uraguchi,D.; Yamada, K.; Sato, M.; *Ooi, T.
J. Am. Chem. Soc.,2018, 140, 5110–5117 - "Catalyst-Enabled Site-divergent Stereoselective Michael Reactions: Overriding Intrinsic Reactivity of Enynyl Carbonyl Acceptors"
Uraguchi,D.; Shibazaki, R.; Tanaka, N.; Yamada, K.; Yoshioka, K.; *Ooi, T.
Angew. Chem. Int. Ed.,2018, 57, 4732-4736 - "Allenedicarboxylate as a Stereochemically Labile Electrophile for Chiral Organic Base-Catalyzed Stereoselective Michael Addition"
Uraguchi,D.; Kawai, Y.; Sasaki, H.; Yamada, K.; *Ooi, T.
Chem. Lett.,2018, 47, 594-597 - "Molecular Design, Synthesis, and Asymmetric Catalysis of a Hexacoordinated Chiral Phosphate Ion"
Uraguchi,D.; Sasaki, H.; Kimura, Y.; Ito, T.; *Ooi, T.
J. Am. Chem. Soc.,2018, 140, 2765-2768 - "Diastereo- and enantioselective phase-transfer alkylation of 3-substituted oxindoles with racemic secondary alkyl halides"
Ohmatsu,K.; Furukawa, Y.; Kiyokawa, M.; *Ooi, T.
Chem. Commun.,2017, 53, 13113-13116
Books
- 「Organic Molecular Catalysts in Radical Chemistry: Challenges Toward Selective Transformations」
Uraguchi, D.; Ohmatsu, K.; Ooi, T.
「Molecular Technology: Synthesis Innovation, Volume 4」,Yamamoto, H., Wiley-VCH,2019, 163-197
Conference
- Symposium on Supramolecular Chemistry in Celebration of Professor Julius Rebek 75th birthday
"Molecular Design of Organic Ions for Asymmetric Catalysis", 口頭発表
大井貴史
10/18/2019-10/18/2019, 上海, 中国 - The First International Symposium on Molecular Recognition and Synthesis
"Molecular Design and Asymmetric Catalysis of Weakly-Coordinating Chiral Anions", 招待講演
大井貴史
10/13/2019-10/13/2019, 上海, 中国 - The 14th International Conference on Cutting-Edge Organic Chemistry in Asia
"「Zwitterionic 1,2,3-Triazolium Amidate as a Catalyst for Photoinduced Hydrogen-Atom Tansfer Radical Alkylation」", ポスター発表
Takashi, Ooi
9/28/2019-9/29/2019, 北海道, 日本 - 2019 International C-H Functionalization Workshop
"Formal Hydroformylation of α,β-Unsaturated Carboxylic Acids under Photoexcited Ketone Catalysis", ポスター発表
Zhu,K.; Ohtani,T.; Tripathi,C.B.; Uraguchi,D.; Ooi,T.
7/11/2019-7/12/2019, Daejeon, South Korea - 2019 International C-H Functionalization Workshop
"Zwitterionic 1,2,3-Triazolium Amidate as a Catalyst for Photoinduced Hydrogen-Atom Transfer Radical Alkylation", ポスター発表
Suzuki,R.; Ohmatsu,K.; Ooi,T.
7/11/2019-7/12/2019, Daejeon, South Korea - 2019 International C-H Functionalization Workshop
"Divergence in Photoredox Reaction: Radical Addition of α-Bromo Nitroalkanes to Styrene Derivatives", 口頭発表
Tsuchiya,Y.; Onai,R.; Uraguchi,D.; Ooi,T.
7/11/2019-7/12/2019, Daejeon, South Korea - Markovnikov Congress on Organic Chemistry
"Molecular Design and Asymmetric Catalysis of Weakly-Coordinating Chiral Anions", 招待講演
Ooi, T.
6/24/2019-6/27/2019, Kazan, Russia - The 1st International Symposium on Hybrid Catalysis for Enabling Molecular Synthesis on Demand
"Zwitterionic 1,2,3-Triazolium Amidate as a Catalyst for Photoinduced Hydrogen-Atom Transfer Radical Alkylation", ポスター発表
Suzuki,R.; Ohmatsu,K.; Ooi,T.
5/30/2019-5/31/2019, Tokyo, Japan - The 1st International Symposium on Hybrid Catalysis for Enabling Molecular Synthesis on Demand
"Divergence in Photoredox Reaction: Radical Addition of α-Bromo Nitroalkanes to Styrene Derivatives", ポスター発表
Onai,R.; Tsuchiya,Y.; Uraguchi,D.; Ooi,T.
5/30/2019-5/31/2019, Tokyo, Japan - The 1st International Symposium on Hybrid Catalysis for Enabling Molecular Synthesis on Demand
"Palladium-Halide Ion Hybrid Catalysis for Base-Free Allylation of Carbonyl Compounds with Allylic Carbonates", ポスター発表
Matsuyama,N.; Ohmatsu,K.; Ooi,T.
5/30/2019-5/31/2019, Tokyo, Japan - SCS Lectureships 2019
"Behavior of Molecules: From Catalysis to Biological Functions", 招待講演
Ooi, T.
5/20/2019-5/24/2019, Geneve, Fribourg, Lausanne, Basel, Zurich, Swiss - Advances in Organocatalysis, SCI
"Molecular design of organic ions for asymmetric catalysis", 招待講演
Ooi, T.
2/25/2019, London, UK - International Conference on Organometallics and Catalysis
"Molecular Design and Asymmetric Catalysis of Weakly-Coordinating Chiral Anions", 招待講演
Ooi, T.
12/13/2018-12/16/2018, Cavelossim, India - ICCC 2018: Post Conference in Nagasaki
"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis", 招待講演
Ooi, T.
11/27/2018-11/30/2018, Nagasaki, Japan - Chinese Chemical Society Chemistry Congress
"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis", 招待講演
Ooi, T.
5/6/2018-5/8/2018, Chengdu, China - 1st International Symposium on Catalysis for Sustainable Chemical Synthesis
"Molecular Design of Organic Ion Pairs for Asymmetric Catalysis", 招待講演
Ooi, T.
9/25/2017-9/26/2017, Freiburg, Germany - 1st International Symposium on Catalysis for Sustainable Chemical Synthesis
"Catalytic Asymmetric Strecker Reaction of Ketoimines with Potassium Cyanide", ポスター発表
Morita, Y.; Ohmatsu, K.; Ooi, T.
9/25/2017-9/26/2017, Freibrug, Germany - 1st International Symposium on Catalysis for Sustainable Chemical Synthesis
"Stereoselective Mannich-type Reaction of Aromatic Lactams under the Catalysis of Chiral Ammonium Betaines", ポスター発表
Kato, K.; Uraguchi, D.; Ooi, T.
9/25/2017-9/26/2017, Freibrug, Germany
Award
- 「Swiss Chemical Society Lectureships 2019」
受賞者：Takashi Ooi
贈呈元：Swiss Chemical Society
受賞日：5/20/2019